Neptunium - Np

General Information

Discovery

Neptunium was discovered by E.M. McMillan and P. Abelson in 1940 in California, USA.

Appearance

Neptunium is a radioactive silvery metal.

Source

Neptunium is obtained as a by-product from nuclear reactors. Trace quantities occur naturally in uranium ores.

Uses

Neptunium is little used outside research.

Biological Role

Neptunium has no known biological role. It is toxic due to its radioactivity.

General Information

Neptunium is attacked by oxygen, steam and acids, but not by alkalis.




  Physical Information    
  Atomic Number   93
  Relative Atomic Mass (12C=12.000)   237.05
  Melting Point/K   913
  Boiling Point/K   4175
  Density/kg m-3   20250 (293K)
  Ground State Electron Configuration   [Rn]5f46d17s2


  Key Isotopes          
  nuclide 237Np        
  atomic mass 237.05        
  natural abundance 0%        
  half-life 2.14x106 yrs        


Other Information  
Enthalpy of Fusion/kJ mol-1 9.46
Enthalpy of Vaporisation/kJ mol-1 336.6
     
Oxidation States  
main NpV
others NpII, NpIII, NpIV, NpVI, NpVII
   
Covalent Bonds /kJ mol-1  
not applicable    
  Ionisation Energies/kJ mol-1
  M - M+ 597
  M+ - M2+  
  M2+ - M3+  
  M3+ - M4+  
  M4+ - M5+  
  M5+ - M6+  
  M6+ - M7+  
  M7+ - M8+  
  M8+ - M9+  
  M9+ - M10+